The paper presents the whole spectrum of topics related to the determination of gases content in
Karat apparatus. The construction of the apparatus is presented, likewise technical instruction of
measurement is described. The paper presents also theoretical grounds of calculations of gases
content in liquids by the use of values obtained on this apparatus and there is also described precision
of the obtained values. Particular attention was paid to the method of calculation of the carbon
dioxide content in water, which was introduced by Fresenius and Grünhut. All existed data are based
on this method. Author has critically analysed this method and proposed the new theoretical grounds
of calculations. These calculations takes into account new, additional paremeters, like: atmospheric
pressure, difference of carbon dioxide concentration in pushed-out water and solobility of
atmospheric gases in the water. Author made an analysis of the accuracy of this new method of
determination the carbon dioxide concntent in water, taking into account the model of water
degassing, uncertainty of the measurement and the way of samples collection. Author has made also
the estimation of the influence of particular measured values on the measurement error.
The new method of calculation gives higher values of measurements, then the method proposed
by Fresenius and Grünhut. Author’s method doesn’t require to apply any empirical improvements
leading to increase of the values obtained from theoretical calculations of the gas concentration in the
water.
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CIĘŻKOWSKI W., DULIŃSKI W., JÓZEFKO I., KIEŁCZAWA B., LIBER–MADZIARZ E., WITCZAK S., ZUBER A., ŻAK S., Występowanie, dokumentowanie i eksploatacja endogenicznego dwutlenku węgla w Polsce – poradnik metodyczny, Wrocł. Tow. Naukowe, Wrocław 2002.
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FRESENIUS R., GRŰNHUT L., Apparat zur angenäherten bestimmung des freien Kohlendioxyds in Mineral Wassern. Zeitschrift fűr Analitysche Chemie, 1914, LIII, s. 265-275.
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